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陆庆全

作者:     点击:      时间:2019-06-05

Prof. Dr. Qingquan Lu

 

教授,博士生导师

联系方式gci2011@whu.edu.cn

主要研究方向:

自由基化学:基于电化学合成、光催化实现惰性化学键的可控重组

金属有机化学:基于过渡金属催化、仿生催化实现手性分子合成

物理有机化学:人工智能在化学合成中的应用

科研及工作经历:

2019.05— 武汉大学高等研究院,教授、博士生导师

2018.09—2019.04 美国圣路易斯华盛顿大学,博士后,合作导师:Prof. Kevin D. Moeller

2015.03—2018.09 德国明斯特大学,博士后、洪堡学者,合作导师:Prof. Frank Glorius

2011.09—2014.12 武汉大学,博士,导师:雷爱文教授

2008.09—2011.06 中国科学技术大学,硕士,导师:王官武教授

荣誉与奖励:

入选国家中组部青年海外高层次人才引进计划2019

德国明斯特大学博士后奖学金(2018

湖北省优秀博士论文(2017

德国亚历山大洪堡奖学金、洪堡学者(2015

爱思唯尔博士生奖全球45人名单(2014

武汉大学十大珞珈风云学子(2014

武汉大学十大杰出青年(学生)2014

博士生国家奖学金(2013

宝钢优秀学生特等奖(2013

主要研究成果:

在氧气引发的自由基反应以及廉价金属催化的偶联反应领域开展了系统性的研究;同时利用在线红外、顺磁、核磁、拉曼、同步辐射等技术手段对反应机理进行了较为深入的研究,并将发展的方法学应用到了生物活性分子、材料分子、药物分子以及手性分子的合成等相关领域中,取得了系列性研究成果。以第一(含共一)作者身份在Angew. Chem., Int. Ed. (7)J. Am. Chem. Soc. (1)ACS Catal. (1)Chem. Sci. (3 )等国际学术权威期刊上发表论文21篇,其中17篇论文为汤森路透JCRQ1区论文,8篇第一(含共一)作者论文入选ESI高被引论文(Highly Cited Paper, top 1%);长期受邀担任Beilstein Journal of Organic Chemistry, Tetrahedron Letters, Chemistry - An Asian Journal, Organic & Biomolecular Chemistry, Chinese Journal of Chemistry等国际期刊的审稿人。

课题组长期招收优秀本科生、研究生、研究助理以及博士后,并面向全球寻找合作研究伙伴,欢迎来信垂询洽谈!联系邮箱:gci2011@whu.edu.cn

We are always looking to recruit highly motivated and suitably qualified undergraduatesgraduates and postdocs, strategic research partners are always welcome! Please, contact me in advance! Email: gci2011@whu.edu.cn

代表性论文:

21.  Q. Lu#, S. Mondal#, S. Cembellín, S. Greßies, F. Glorius.* “Site-selective C–H Activation and Regiospecific Annulation Using Propargylic Carbonates”, Chem. Sci. 2019, 10, 6560-6564.

20.  Q. Lu, S. Mondal, S. Cembellín, S. Singha, F. Glorius.* “Mn(I)/Ag(I) Relay Catalysis: Traceless Diazo-Assisted C(sp2)–H/C(sp3)–H Coupling to b-(Hetero)Aryl/Alkenyl Ketones”, Angew. Chem., Int. Ed. 2018, 57, 57, 10732-10736.

19.  Q. Lu, S. Cembellín, S. Greßies, S. Singha, F. Glorius.* “Manganese(I)-Catalyzed C–H (2-Indolyl)methylation: Expedient Access to Diheteroarylmethanes”, Angew. Chem., Int. Ed. 2018, 57, 1399-1403. (Highly Cited Paper, 2018-2019)

18.  Q. Lu#, S. Greßies#, S. Cembellín, F. J. R. Klauck, C. G. Daniliuc, F. Glorius.* “Redox-Neutral Manganese(I)-Catalyzed C–H Activation: Traceless Directing Group Enabled Regioselective Annulation”, Angew. Chem., Int. Ed. 2017, 56, 12778-12782. (Hot Paper Selected by the Editors, Highly Cited Paper, 2019)

17.  Q. Lu, S. Greßies, F. J. R. Klauck, F. Glorius.* “Manganese(I)-Catalyzed Regioselective C-H Allenylation: Direct Access to 2-Allenylindoles”, Angew. Chem., Int. Ed. 2017, 56, 6660-6664. (Highly Cited Paper, 2018-2019)

16.  Q. Lu, F. Glorius.* “Radical Enantioselective C(sp3)–H Functionalization”, Angew. Chem., Int. Ed. 2017, 56, 49-51. (Most Accessed Papers in 2017)

15.  Q. Lu, F. J. R. Klauck, F. Glorius.* “Manganese-Catalyzed Allylation via Sequential C–H and C–C/C–Het Bond Activation”, Chem. Sci. 2017, 8, 3379-3383. (Highly Cited Paper, 2018-2019)

14.  H. Wang#, Q. Lu#, C. Qian, C. Liu, W. Liu, K. Chen, A. Lei.* “Solvent Enabled Radical Selectivities: Controlled Syntheses of Sulfoxides and Sulfides”, Angew. Chem., Int. Ed. 2016, 55, 1094-1097. (Highly Cited Paper, 2018)

13.  Q. Lu, S. Vásquez-Céspedes, T. Gensch, F. Glorius.* “Control over Organometallic Intermediate Enables Cp*Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles”, ACS Catal. 2016, 6, 2352-2356. (Highly Cited Paper, 2018-2019)

12.  Q. Lu#, J. Zhang#, P. Peng, G. Zhang, H. Zhang, H. Yi, J. T. Miller, A. Lei.* “Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis”, Chem. Sci. 2015, 6, 4851-4854.

11.  Q. Lu, J. Zhang, G. Zhao, Y. Qi, H. Wang, A. Lei.* “Dioxygen-Triggered Oxidative Radical Reaction: Direct Aerobic Difunctionalization of Terminal Alkynes toward β‑Keto Sulfones”, J. Am. Chem. Soc. 2013, 135, 11481-11484. (Monthly Most Accessed Paper, Highly Cited Paper, 2018-2019)

10.  Q. Lu, J. Zhang, F. Wei, Y. Qi, H. Wang, Z. Liu, A. Lei.* “Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary b-Hydroxysulfones”, Angew. Chem., Int. Ed. 2013, 52, 7156-7159. (Highly Cited Paper, 2018-2019)

9.  Z. Huang#, Q. Lu#, Y. Liu, D. Liu, J. Zhang, A. Lei.* “Regio- and Stereoselective Oxysulfonylation of Allenes”, Org. Lett. 2016, 18, 3940-3943.

8.  Q. Lu#, P. Peng#, Y. Luo, Z. Zhao, M. Zhou, A. Lei.* “Copper-Catalyzed Aerobic Decarboxylation/Ketooxygenation of Electron-Deficient Alkenes”, Chem. Eur. J. 2015, 21, 18580-18583.

7.  Q. Lu, Z. Liu, Y. Luo, G. Zhang, Z. Huang, H. Wang, C. Liu, J. T. Miller, A. Lei.* “Copper-/Cobalt-Catalyzed Highly Selective Radical Dioxygenation of Alkenes”, Org. Lett. 2015, 17, 3402-3405.

6.  Q. Lu, H. Wang, P. Peng, C. Liu, Z. Huang, Y. Luo, A. Lei.* “Autoinductive thiolation/oxygenation of alkenes at room temperature”, Org. Chem. Front., 2015, 2, 908-912.

5.  Q. Lu, J. Chen, C. Liu, Z. Huang, P. Peng, H. Wang, A. Lei.* “O2-Mediated C(sp2)−X Bonds Oxygenation: Autoxidative Carbon-Heteroatom Bonds Formation Using Activated Alkenes as Linkage”, RSC Adv., 2015, 5, 24494-24498.

4.  Q. Lu, H. Yi, A. Lei.* “Autoxidative Coupling and Its Applications to C-H Functionalization”, Acta Chim. Sinica. 2015, 73, 1245-1249.

3.  Q. Lu#, C. Liu#, Z. Huang, Y. Ma, J. Zhang, A. Lei.* “Relay cooperation of K2S2O8 and O2 in oxytrifluoromethylation of alkenes using CF3SO2Na”, Chem. Commun. 2014, 50, 14101-14104.

2. Q. Lu, C. Liu, P. Peng, Z. Liu, L. Fu, J. Huang, A. Lei.* “Copper-Catalyzed Trifluoromethylation-Initiated Radical Oxidative Annulation toward Oxindoles”, Asian J. Org. Chem. 2014, 3, 273-276.

1.  G.-W. Wang,* Q.-Q. Lu, and J.-J. Xia,* “Three Types of Products Obtained Unexpectedly from the Reaction of Dimedone with Chalcones”, Eur. J. Org. Chem. 2011, 4429-4438.